Cover Feature: Synthesis and Lewis Acid Properties of Neutral Silver(III) Adducts Containing the AgIII(CF3)3 Moiety (Chem. Eur. J. 43/2024)

Autor: Demonti, Luca, Joven‐Sancho, Daniel, Saffon‐Merceron, Nathalie, Baya, Miguel, Nebra, Noel
Zdroj: Chemistry - A European Journal; Aug2024, Vol. 30 Issue 43, p1-1, 1p
Abstrakt: Shedding light on the three AgIII species on stage that were authenticated while attempting the isolation of [AgIII(CF3)3(NCCH3)] (2) by protonolysis of [AgIII(CF3)4]− (1) (left spotlight), or alternatively, through chloride abstraction from [AgIII(CF3)3Cl]− (3⋅Cl) (right spotlight). In this Cover Feature, the structure of the lead player 2 is depicted at the forefront. Strikingly, two supporting actors, [AgIII(CF3)3(C6H9N3)] (2’) and the AgIII‐ONO2 complex 5, came on the scene in this production and are illustrated here on a second plane, yet illuminated by the two spotlights that allowed their neat identification. The s‐triazinyl core forged through trimerization likewise symbolizes the trans‐Pyrenean bridges built between our teams located in Zaragoza and Toulouse. More information can be found in the Research Article by M. Baya, N. Nebra and co‐workers (DOI: 10.1002/chem.202400881). Graphic design by Pablo Falcón‐Buedo. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index