| Autor: |
Singh, Suraj, Kumar, Rohtash, Dubey, Navneet Nandgopal, Appayee, Chandrakumar |
| Předmět: |
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| Zdroj: |
Chemical Communications; 8/25/2024, Vol. 60 Issue 66, p8768-8771, 4p |
| Abstrakt: |
The first synthesis of chiral cis-2,5-disubstituted pyrrolidine organocatalysts is described. Their application for the enantioselective Michael addition of nitromethane to α,β-unsaturated aldehydes with excellent yield (up to 91%) and enantioselectivity (up to >99% ee) is demonstrated. Another catalytic application for the reaction of 2,4-hexadienal with nitrostyrene is also showcased. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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