| Autor: |
Yuan, Yuan, Zhang, Dong-Hui, Li, Qiao-Hong, Chen, Shu-Mei, He, Yan-Ping, Zhang, Jian |
| Předmět: |
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| Zdroj: |
Chemical Communications; 8/25/2024, Vol. 60 Issue 66, p8748-8751, 4p |
| Abstrakt: |
The integration of anionic Ti4L6 (L = embonate) cages and π-conjugated coordination cations into ordered structures can produce high-performance nonlinear optical (NLO) materials. More specifically, by employing Ti4L6 cages for assembly with mixed N,N-chelated and P,P-chelated type conjugated organic ligands and Ag+ ions, three cage-based structures have been synthesized and structurally characterized. Among them, an ion pair structure with strong π–π accumulation exhibits a significant third-order NLO response, and an excellent optical limiting effect has been experimentally verified. This work provides a promising material for NLO applications. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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