| Autor: |
Wang, Qianhang, Wang, Yarong, Zhao, Yue, Li, Yang, Jiang, Wenfeng, Bai, Wei |
| Předmět: |
|
| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 8/21/2024, Vol. 53 Issue 31, p12872-12875, 4p |
| Abstrakt: |
The oxidation state of the metal center is important for a conjugated metallacycle. Although high valent d0-metallacycles of main groups and early transition metals have been reported, such examples of late transition metals are limited. The reactions of ReOCl3(PPh3)2 with 2-ethynyl anilines produced alkenyl amino Re(V) complexes, which can be further oxidized to Re(VII) aza-metallacycles. The conjugated rhenacycle is nonaromatic, however, with close to zero NICS values and localized currents observed by AICD and GIMIC studies. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
