| Autor: |
Miyazaki, Kanako, Nakata, Kenya |
| Předmět: |
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| Zdroj: |
Synlett; Aug2024, Vol. 35 Issue 13, p1591-1595, 5p |
| Abstrakt: |
Chiral guanidine-catalyzed acylative and silylative dynamic kinetic resolutions of 6-hydroxy-2 H -pyran-3(6 H)-one were achieved. We succeeded in developing a non-enzymatic acylative dynamic kinetic resolution of 6-hydroxy-2 H -pyran-3(6 H)-one with high enantioselectivity, which could be improved by recrystallization. In contrast, the non-enzymatic silylative dynamic kinetic resolution of 6-hydroxy-2 H -pyran-3(6 H)-one was accomplished with a moderate selectivity for the first time. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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