Stepwise construction of a metallocatenane based on non-labile bis(terpyridine)-CdII complexes.

Autor: Wang, Shih-Yu, Lin, Lin-Ting, Rani, Alisha, Lee, Guan-Sian, Chan, Yi-Tsu
Předmět:
Zdroj: Chemical Communications; 8/7/2024, Vol. 60 Issue 61, p7914-7917, 4p
Abstrakt: A series of metalloligands bearing homoleptic 2,2′:6′,2′′-terpyridine (tpy)-CdII complexes has been successfully synthesized. The formation of ML1 was accomplished through a sequence of Suzuki–Miyaura coupling and complexation reactions, offering an alternative method to produce tpy-based metalloligands under relatively mild conditions. Moreover, the metallomacrocycle C1 and metallocatenane C2 were self-assembled from heteroleptic complexation reactions involving ML1 and suitable counterparts. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index