Luminescent, low-toxic P,P-bischelate copper(i) complexes with N-alkylaryl-substituted 1,5-diaza-3,7-diphosphacyclooctanes.

Autor: Dayanova, I. R., Sabirova, Z. R., Lyubina, A. P., Voloshina, A. D., Shmelev, A. G., Musina, E. I., Strelnik, I. D., Karasik, A. A.
Předmět:
Zdroj: Russian Chemical Bulletin; Jun2024, Vol. 73 Issue 6, p1811-1817, 7p
Abstrakt: The interaction of 2-(thiophen-2′-yl)ethylphosphine, paraformaldehyde, and benzhydrylamine or 1-methylbenzylamine resulted in 1,5-diaza-3,7-diphosphacyclooctanes, which were used for the synthesis of P,P-bischelate copper(i) complexes. The obtained compounds were characterized by NMR spectroscopy, mass spectrometry, and elemental analysis. The study of the luminescent properties of the copper(i) complexes demonstrated that they are solid-state singlet luminophores. Their biological activity was investigated. They were shown to be inactive against gram-positive and gram-negative bacteria and exhibited a low cytotoxicity, which determined their potential use as luminescent sensors for biological applications. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index