Dinitrogen activation at chromium by photochemically induced CrII–C bond homolysis.

Autor: Duletski, Olivia L., Platz, Duncan, Pollock, Charlie J., Mosquera, Martín A., Arulsamy, Navamoney, Mock, Michael T.
Předmět:
Zdroj: Chemical Communications; 7/14/2024, Vol. 60 Issue 55, p7029-7032, 4p
Abstrakt: The synthesis of the organochromium(II) complexes [POCOPtBu]Cr(R) (R = p-Tol, Bn) is reported. Exposure of [POCOPtBu]Cr(Bn) to visible light promoted homolytic Cr–CBn bond cleavage and formed {[POCOPtBu]Cr}211μ-N2) via a putative [POCOPtBu]Cr(I) species. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index