Isolation of a copper photocatalyst on a metal–organic cage for the sulfonylation of aryl halides resulting from visible-light-mediated C(sp2)–S cross-coupling.

Autor: Zhao, Lehua, Zhang, Yu, Wang, Huali, Wang, Jing, He, Cheng, Zhao, Liang, Duan, Chunying
Předmět:
Zdroj: Chemical Communications; 7/7/2024, Vol. 60 Issue 53, p6805-6808, 4p
Abstrakt: A Ce-based metal–organic tetrahedron was assembled for preserving the uncoordinated nature of 2,2′-bipyridyl groups to form a Cu-based photocatalyst, which protected CuI centers from intermolecular deactivation and showed high photocatalytic activity for the visible-light-mediated C(sp²)−S cross-coupling. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index