Synthesis of functionalized phosphorus-substituted derivatives of γ-butyrolactone.

Autor: Bubnov, Yu. N., Prishchenko, A. A., Livantsov, M. V., Novikova, O. P., Livantsova, L. I., Baranin, S. V.
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Zdroj: Russian Chemical Bulletin; May2024, Vol. 73 Issue 5, p1386-1393, 8p
Abstrakt: A convenient synthesis of functionalized phosphorus-substituted derivatives of γ-butyrolactone based on readily available γ-crotonolactone and trimethylsilyl esters of trivalent phosphorus acids has been developed. The addition of bis(trimethylsiloxy)phosphine to γ-crotonolactone proceeds regioselectively to give phosphonites containing γ-butyrolactone moieties, the subsequent functionalization of which leads to a variety of target derivatives. The resulting compounds are of interest as promising biologically active substances and water-soluble ligands. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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