| Autor: |
Liu, Xiaochen, Hee, Samual, Sapir, Netanel G., Li, Alvin, Liu, Jianbo, Chen, Yu |
| Předmět: |
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| Zdroj: |
Advanced Synthesis & Catalysis; 6/10/2024, Vol. 366 Issue 11, p2489-2494, 6p |
| Abstrakt: |
n‐Bu4NI/K2S2O8 mediated transformylation from p‐anisaldehyde to primary amides is reported. The mechanistic studies suggest the reaction occurs via a single electron transfer pathway. Based on the DFT electronic structure calculations of various reaction pathways, the most plausible mechanism involves the formation of a phenyl radical cation and an arenium ion as the key intermediates. It represents the first example where p‐anisaldehyde is employed as a formyl source via a non‐metal mediated Csp2−Csp2 bond cleavage. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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