ВЛАСТИВОСТІ КОМПОЗИЦІЙНОГО ПАЛИВА НА ОСНОВІ ПІРОКАРБОНУ - ПРОДУКТУ ПІРОЛІЗУ ШИН

Autor: Макаров, А. С., Шкуткова, О. В., Кліщенко, Р. Є., Лисенко, Л. Л., Косигіна, І. М., Зінін, В. В., Коновал, О. А.
Zdroj: Issues of Chemistry & Chemical Technology / Voprosy Khimii & Khimicheskoi Tekhnologii; Apr2024, Issue 2, p61-69, 9p
Abstrakt: The possibility of utilizing technical pyrocarbon, produced by the pyrolysis of used automobile tires, in a composite suspension fuel is demonstrated. It has been found that pyrocarbon-based systems without additives are not suitable for use as fuel due to thickening and hydrophobic properties. To improve the properties of the composite suspension fuels, the influence of stabilizer, plasticizer, and dispersant additives on the rheological properties of the composite suspension fuel was investigated. Carboxymethyl cellulose, sodium lignosulfonate, NF, C-3 (a condensation product of β-naphthalene sulfonic acid and formaldehyde), and humic acids were used as additives. It was determined that the surface of unmodified pyrocarbon has a positive surface charge in the pH range of 2-10. Addition of reagents induces a change in the surface charge of pyrocarbon and surface recharging. It is shown that the best results in composite suspension fuel compositions are achieved with the addition of C-3 at a concentration of 2 wt.%. The effective viscosity of the obtained suspensions at a shear rate of 9 s-1 does not exceed 0.8 Pa⋅s. This allows the use of the obtained systems with additives as liquid suspension fuels. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index