Stereoregular poly(2-phenylthiirane) via cationic ring-opening polymerization.

Autor: Yu Xiao, Tian-Jun Yue, Xiao-Bing Lu, Wei-Min Ren
Předmět:
Zdroj: Chemical Communications; 5/11/2024, Vol. 60 Issue 38, p5034-5037, 4p
Abstrakt: Herein, we describe an effective strategy for synthesizing polythioethers with a well-defined structure through the cationic polymerization of thiirane with electron-withdrawing substituents. This strategy allows for precisely controlling the regio- and stereochemistry of the ring-opening polymerization of 2-phenylthiirane, thus allowing for producing poly(2-phenylthiirane) with high stereoregularity using enantiomeric pure thiirane. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index