Alkene versus Aryl Chlorination in Asymmetric Hypervalent Iodine Catalysis: A Case Study.

Autor: Arnold, Andreas M., Binder, Julia, Kretzschmar, Martin, Gulder, Tanja
Předmět:
Zdroj: Synlett; Jun2024, Vol. 35 Issue 9, p1001-1006, 6p
Abstrakt: This article explores the use of hypervalent iodanes as catalysts in organic synthesis, specifically focusing on the chlorination of substrates. The authors investigate the use of iodoresorcinol lactate as a catalyst for enantioselective chlorinations, but encounter challenges with aromatic chlorination. They also discuss the need for further analysis of catalyst integrity in chlorination reactions. The authors are currently working on developing stereoselective chlorination-mediated reactions based on their findings. [Extracted from the article]
Databáze: Complementary Index