C(5)—H arylation of 1-substituted 1,2,4-triazoles with aryl halides under Pd/NHC catalysis.

Autor:	Astakhov, A. V., Chernenko, A. Yu., Kutyrev, V. V., Chernyshev, V. M.
Předmět:	ARYL halides ARYL chlorides ARYLATION ARYL bromides CATALYSIS PALLADIUM compounds
Zdroj:	Russian Chemical Bulletin; Apr2024, Vol. 73 Issue 4, p950-956, 7p
Abstrakt:	An efficient method for the synthesis of 1-substituted 5-aryl-1,2,4-triazoles by selective C—H arylation of 1-substituted 1,2,4-triazoles with non-activated aryl chlorides and aryl bromides under the catalysis by a palladium complex with a N-heterocyclic carbene ligand IPr*OMe using 1,1,2,2-tetraphenylethane-1,2-diol (TPEDO) as a catalyst activator is reported. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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