| Autor: |
Waghchoure, Aishwarya P., Narode, Hanuman, Sangale, Vijay B., Siddiqui, Zahir Ali, Sarkhel, Sanchita, Pardeshi, Satish K., Jaiswal, Amit, Sekar, Nagaiyan, More, Sandeep, Bhosale, Rajesh S. |
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| Zdroj: |
ChemistrySelect; 4/18/2024, Vol. 9 Issue 15, p1-8, 8p |
| Abstrakt: |
In this work, short π‐conjugated (Z)‐2‐(4‐(2‐cyano‐2‐phenylvinyl)phenoxy)‐N‐(1‐(3‐ethoxy‐4‐methoxyphenyl)‐2‐(methyl sulfonyl)ethyl)acetamide (CYS) and large π‐conjugated 2,2′‐(((1Z,1′Z)‐1,4‐phenylenebis(2‐cyanoethene‐2,1‐diyl))bis(4,1‐phenyl ene))bis(oxy))bis(N‐(1‐(3‐ethoxy‐4‐methoxyphenyl)‐2‐(methyl sulfonyl)ethyl)acetamide (BCYS) compounds were synthesized. Furthermore, the influence of π‐conjugation length on CYS and BCYS absorption, fluorescence, aggregation induced emission (AIE) characteristics, and self‐assembly was examined. The large π‐conjugated BCYS (π‐conjugation length=18.71 Å) exhibits AIE property getting on in the DMSO−Water solvent combination as the volume % of water increases and demonstrated production of self‐assembled bundle of micro fibrous structure of around 5 to 6 microns long and 200 to 500 nm wide. Short π‐conjugated CYS (π‐conjugation length=10.80 Å), on the other hand, exhibits aggregation caused quenching (ACQ) in the DMSO−Water solvent combination as the volume % of water increases and the creation of self‐assembled nanostructured crystalline asymmetrical particles. Moreover, the cytotoxicity study of CYS and BCYS revealed that BCYS had superior biocompatibility than CYS. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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