| Autor: |
Ebert, Max, Lange, Alyna, Müller, Michael, Wuckert, Eugen, Gießelmann, Frank, Klamroth, Tillmann, Zens, Anna, Taubert, Andreas, Laschat, Sabine |
| Zdroj: |
Physical Chemistry Chemical Physics (PCCP); 4/21/2024, Vol. 26 Issue 15, p11988-12002, 15p |
| Abstrakt: |
Ionic liquid crystals (ILCs) combine the ion mobility of ionic liquids with the order and self-assembly of thermotropic mesophases. To understand the role of the anion in ILCs, wedge-shaped arylguanidinium salts with tetradecyloxy side chains were chosen as benchmark systems and their liquid crystalline self-assembly in the bulk phase as well as their electrochemical behavior in solution were studied depending on the anion. Differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (WAXS, SAXS) experiments revealed that for spherical anions, the phase width of the hexagonal columnar mesophase increased with the anion size, while for non-spherical anions, the trends were less clear cut. Depending on the anion, the ILCs showed different stability towards electrochemical oxidation and reduction with the most stable being the PF6 based compound. Cyclic voltammetry (CV) and density functional theory (DFT) calculations suggest a possible contribution of the guanidinium cation to the oxidation processes. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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