Reversible open–closed conformational switching of nano-size metalloporphyrin dimers triggered by light and temperature.

Autor: Shah, Syed Jehanger, Singh, Ajitesh, Goswami, Debabrata, Ishida, Masatoshi, Rath, Sankar Prasad
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 4/21/2024, Vol. 53 Issue 15, p6758-6765, 8p
Abstrakt: The current work demonstrates the reversible control of substantial molecular motion in 'nano-sized' molecules, where two structural isomers can 'open' and 'close' their cavities in response to light or heat. The isomers differ widely in their photophysical properties, including colour, polarity, two-photon absorption and π-conjugation, and can easily be separated through column chromatography and thus have wide applicability. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index