Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22.

Autor: Röβ-Ohlenroth, Richard, Knippen, Katharina, Kraft, Maryana, Volkmer, Dirk
Předmět:
Zdroj: CrystEngComm; 4/21/2024, Vol. 26 Issue 15, p2051-2055, 5p
Abstrakt: Enantioselective enrichment of R- or S-1-phenylethanol from racemic mixtures, reaching up to 42% enantiomeric excess and >60 wt% loading in the chiral CFA-22 (Coordination Framework Augsburg-22) metal–organic framework prepared from novel, scalable, and readily available camphor-based ligands, is demonstrated through single-crystal X-ray studies in conjunction with chiral high-performance liquid chromatography. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index