| Autor: |
Liu, Ruzhang, Wang, Juan, Wu, Hao, Quan, Xianfeng, Wang, Shilin, Guo, Jiandong, Wang, Yang, Li, Heting |
| Předmět: |
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| Zdroj: |
Chemical Communications; 4/25/2024, Vol. 60 Issue 32, p4362-4365, 4p |
| Abstrakt: |
A selective intermolecular Schmidt reaction of equilibrating hydroxyalkyl allylic azides is reported to afford N-hydroxyalk-1-en-3-yl lactams in modest to high yields. For prochiral and chiral ketones, modest to high 1,5-diastereoselectivity was achieved, and the mechanistic analysis is supported by DFT calculation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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