Access to Versatile Functionalized Cu(III) Complexes Enabled by Direct Transmetalation to Well‐Defined Copper(III) Fluoride Complex Me4N+[Cu(CF3)3F]‐.

Autor: Wang, Guangyu, Li, Huaiyuan, Leng, Xuebing, Lu, Long, Shen, Qilong
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Zdroj: Chinese Journal of Chemistry; May2024, Vol. 42 Issue 10, p1107-1113, 7p
Abstrakt: Comprehensive Summary: The invention of a well‐defined Cu(III) fluoride complex Me4N+[Cu(CF3)3(F)]‐1 enabled to access a versatile of functionalized Cu(III) complexes [Me4N]+[Cu(X)(CF3)3]‐ (X = C6F5, C6F5C≡C, CN, Cl, N3, tBuOO, SCN, OAc, SAr), many of them for the first time. The availability of these complexes allowed us to evaluate the trans‐influence order of ligand in Cu(III) complexes: Bn > CF3– > C6F5– > N3– > py ~ CH3– ~ C6F5C≡C > NO2PhO– ~ tBuOO– ~ CH3COO– > F–. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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