(N , N ′-Di- tert -butyl- S -phenylsulfinimidamidato-κ N ,κ N ′)-chlorogermanium-κ Ge -chloro(η 2 , η 2 -cycloocta-1,5-diene)rhodium.

Autor:	Hosoda, Narimi, Ishii, Akihiko, Nakata, Norio
Předmět:	RHODIUM MOLECULAR structure CARBON monoxide X-ray diffraction NUCLEAR magnetic resonance spectroscopy PLATINUM
Zdroj:	Molbank; Mar2024, Vol. 2024 Issue 1, pM1781, 6p
Abstrakt:	The title complex [{PhS(tBuN)2}(Cl)Ge:→RhCl(cod)] (2) was synthesized by the reaction of three-coordinated chlorogermylene, [PhS(tBuN)2]GeCl (1), supported by a diimidosulfinate ligand with a half equivalent of [RhCl(cod)]2 in benzene. The molecular structure of 2 was determined by 1H and 13C NMR spectroscopies and single-crystal X-ray diffraction (SCXRD) analysis. The electronic property of germylene 1 was assessed by determining the Tolman electronic parameter of the corresponding cis-dicarbonyl Rh(I) complex, [{PhS(tBuN)2}(Cl)Ge:→RhCl(CO)2] (3), that was prepared by the treatment of 2 with carbon monoxide. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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