| Abstrakt: |
We present the atomic structures and nonequilibrium synthesis of a new class of materials, where the basic structural unit is a diamond tetrahedron. When units of one, two, and three tetrahedra are randomly packed, we create distinct phases of amorphous Q-carbon. Four tetrahedra in two adjacent layers lead to crystalline diamond lattice, which has four missing tetrahedra alternately. When these four missing tetrahedra are filled, we create subunit cell of crystalline Q-diamond. Theoretical calculations show that the superconducting transition temperature (Tc) in 50 atomic % B-doped Q-diamond can reach room temperature at ambient pressures. This is consistent with our earlier results using low-loss EELS measurements in 50 atomic % B-doped Q-carbon, which had mostly amorphous QB3 phase mixed with some crystalline Q-diamond phase. These EELS results showed that the Tc for these samples was between 90 K and 300 K. Theoretical calculations of density of states, Eliashberg function, electron–phonon interaction parameter, and root-mean-square and logarithmic average of frequency in crystalline Q-diamond show Tc in the range of 268 K to 300 K, which is in complete agreement with our EELS results in QB3. [ABSTRACT FROM AUTHOR] |
