| Autor: |
Astakhov, E. A., Kazakov, I. V. |
| Předmět: |
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| Zdroj: |
Russian Journal of General Chemistry; 2024 Suppl 1, Vol. 94, pS36-S39, 4p |
| Abstrakt: |
The thermal stability of the [tBu3PH][HB(C6F5)3] complex, which is a product of molecular hydrogen activation by the tBu3P·B(C6F5)3 frustrated Lewis pair (FLP), was studied using a static tensimetric method with a membrane null-manometer. It was found that heating [tBu3PH][HB(C6F5)3] to temperatures above 430 K is accompanied by thermal dissociation with passing into vapor of molecular hydrogen, pentafluorobenzene, and 2-methylpropene, as the main volatile products. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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