| Abstrakt: |
A possible way to reduce the size and complexity of common gas chromatography (GC) systems is the economization of the column temperature regulation system. To this end, a temperature compensation method was developed and validated on a benchtop GC-PDD (pulsed discharge detector) with ethene. An in-house-developed algorithm correlates the retention index of a test gas to the retention index of a previously selected reference gas. To investigate further methods of cost reduction, commercial gas sensors were tested as cheap, sensitive, and versatile detectors. Therefore, CO 2 was chosen as a naturally occurring reference gas, while ethene was chosen as a maturity marker for climacteric fruits and hence as a test gas. A demonstrator, consisting of a simple syringe injection system, a PLOT (porous layer open tubular) column boxed in a polystyrene-foam housing, a commercial MOS (metal-oxide semiconductor) sensor for the test gas, and a CO 2 -specific IR (infrared) sensor, was used to set up a simple GC system and to apply this method on test measurements. Sorption parameters for ethene and CO 2 were determined via a van 't Hoff plot, where the entropy S was -11.982 J mol -1 K -1 ΔSEthene0 and 1.351 J mol -1 K -1 ΔSCarbondioxide0 , and the enthalpy H was -20.622 kJ mol -1 ΔHEthene0 and -14.792 kJ mol -1 ΔHCarbondioxide0 , respectively. Ethene (100 ppm) measurements revealed a system-specific correction term of 0.652 min. Further measurements of ethene and interfering gases revealed a mean retention time for ethene of 3.093 min; the mean predicted retention time is 3.099 min. The demonstrator was able to identify the test gas, ethene, as a function of the reference gas, CO 2 , in a first approach, without a column heating system and in a gas mixture by applying a temperature compensation algorithm and a system-specific holdup time correction term. [ABSTRACT FROM AUTHOR] |
