Molecular and Crystal Structures of Ethyl-2-Amino-2-Bis(3,5-di-Tert-Butyl-4-Hydroxybenzyl)Ethanoate. Hydrogen Bonds in the Crystals of Sterically Hindered Phenols.

Autor: Litvinov, I. A., Bukharov, S. V., Tagasheva, R. G., Bogdanov, A. V., Zamaletdinova, D. M.
Předmět:
Zdroj: Journal of Structural Chemistry; Feb2024, Vol. 65 Issue 2, p281-288, 8p
Abstrakt: Ethyl-2-amino-2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)ethanoate is prepared, its molecular and crystal structures are studied. The H-bond system in the crystals of compounds containing sterically hindered phenolic groups is analyzed. It is shown that a disproportion of proton-donor and proton-accepting groups in crystals may lead to the formation of an H-bond system in which hydroxyl and amino groups are not involved in hydrogen bonding. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index