Smart nanocomposites: Harnessing magnetically recoverable MWCNT-CF for efficient organic dyes reduction in water quality monitoring applications.

Autor: Thombare, Balu R., Daware, Krishna D., Khupse, Nagesh, Dusane, Pravin R., Lole, Gaurav S., Khedkar, Chaitali V., Badgujar, Prashant S., Bankar, Prashant K., Patil, Shankar I.
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Zdroj: AIP Advances; Feb2024, Vol. 14 Issue 2, p1-8, 8p
Abstrakt: The accelerating use of organic dyes in various industries has led to a surge in water pollution, especially from non-biodegradable dye effluents discharged into water resources. This study addresses the critical issue of catalyzing the reduction of two prevalent dyes, methylene blue (MB) and rhodamine-B (RhB), using a multiwalled carbon nanotube-cobalt ferrite (MWCNT-CF) nanocomposite. The synthesized nanocomposite demonstrates exceptional catalytic activity, stability, and recyclability. Conventional methods for treating dye-containing wastewater often prove expensive. This study explores the efficacy of catalytic reduction, a relatively fast process facilitated by semiconductor nanoparticles. Structural analyses using X-ray diffraction and high-resolution transmission electron microscopy (HRTEM) confirm the formation of the nanocomposite, revealing unsaturated surface bonds and chains conducive to adsorption. The nanocomposite exhibits a remarkable reduction in both dyes, with easy recyclability for multiple cycles. Magnetization studies confirm the ferrimagnetic nature of the nanocomposite, facilitating its efficient separation from the reaction mixture using a magnet. The study delves into the kinetics of the catalytic reduction following pseudo-first-order kinetics. The surface modifications of the nanocomposite, as revealed by TEM, contribute to enhanced adsorption and catalytic efficiency. Notably, the MWCNT-CF nanocomposite demonstrates negligible loss of catalytic activity during recycling, highlighting its potential for cost-effective and sustainable applications in dye reduction across various industries. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index