| Autor: |
Kato, Hiroki, Fukuhara, Yuki, Miyazaki, Ryuya, Muto, Kei, Yamaguchi, Junichiro |
| Předmět: |
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| Zdroj: |
Asian Journal of Organic Chemistry; Feb2024, Vol. 13 Issue 2, p1-5, 5p |
| Abstrakt: |
A Pd‐catalyzed cyclization/1,4‐difunctionalization of bromoarenes bearing a carbon nucleophile with diazo compounds has been developed. The present reaction proceeds through a π‐benzyl palladium intermediate, whose reactivity is a key for the remarkable 1,4‐selectivity of this reaction, providing functionalized indans and tetralins. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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