Improvement in the Performance of Composite Cathode via Solid Electrolyte for High Electrochemical Performance of Li–S Battery.

Autor: Patodia, Tarun, Sahu, Rajesh, Tripathi, Balram, Ichikawa, Takayuki, Jain, Sushil Kumar, Jain, Ankur
Předmět:
Zdroj: Macromolecular Symposia; Feb2024, Vol. 413 Issue 1, p1-6, 6p
Abstrakt: Commercialization of Li–S in present scenario is obstructed by poor performance of cathode and its compatibility with electrolyte used. Here in this work, in order to improve the electrochemical performance all solid state Li–S battery, solid electrolyte (SE) formed by composition of lithium sulfide (Li2S) and phosphorus pentasulfide (P2S5) combinedly called LPS is used. The modified carbon in the form of graphene oxide (GO) and reduced graphene oxide (rGO) as additive is used to provide better electron conduction pathway. High conductivity of the order 10−4 S cm−1 of prepared LPS overcomes the major drawback of insulating nature of sulfur. The coin cells are fabricated by using above mentioned material as a cathode material, LPS as SE, and lithium foil as anode. The prepared nanocomposites are characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM) to study structural and morphological properties. Energy dispersive X‐ray spectroscopy (EDS) images of the cathode surface confirms the uniform spreading of material. The electrochemical performance of coin cell is studied by Galvanostatic charge‐discharge plot at 0.1 C to check the compatibility of composite and electrolyte prepared. The cells having additive material GO and rGO with host sulfur show better results as compared to the cell having pristine sulfur. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index