Transition‐Metal‐Free C−H Alkylation of Cyclic Aldimines with Alkylboronic Acid.

Autor: Zhou, Yu, Cui, Yangbo, Huang, Hangfei, Zhang, Jun‐Qi, Xu, Yang, Ren, Hongjun, Dong, Zhi‐Bing
Předmět:
Zdroj: European Journal of Organic Chemistry; 2/12/2024, Vol. 27 Issue 6, p1-4, 4p
Abstrakt: Molecular oxygen‐mediated C−H bond alkylation of cyclic aldimines has been reported, which avoids the use of transition metals and additional oxidants. This method allows straightforward access to a series of cyclic aldimine derivatives through a free radical course. Furthermore, this transformation features mild conditions, excellent yields and good functional group tolerance. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index