| Autor: |
Voinova, V. V., Neumolotov, N. K., Zhdanov, A. P., Selivanov, N. A., Bykov, A. Yu., Yakimanskiy, A. A., Chulkova, T. G., Yakimansky, A. V., Zhizhin, K. Yu., Kuznetsov, N. T. |
| Zdroj: |
Russian Journal of Inorganic Chemistry; Dec2023, Vol. 68 Issue 14, p1929-1933, 5p |
| Abstrakt: |
In this study, the reaction of the [B10H11]– anion with phenanthrene-9,10-dicarbonitriles containing various substituents has been studied. A series of new mono- and disubstituted nitrile derivatives of the closo-decaborate anion have been obtained, and the structures of the target products of mono- and disubstitution of general composition [B10H9NCR]– and [(B10H9NC)2R]2– (where R is phenanthrene containing substituents in positions 1 and 10) have been determined. Along with the formation of the target product, a series of unexpected side reactions associated with the protonation of the polyaromatic systems by the [B10H11]– anion have been revealed. The structures and compositions of the products have been determined using 1H, 11B, 13C NMR spectroscopies and mass spectrometry. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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