| Abstrakt: |
Optimizing mechanical performance is crucial for the practical utilization of stimuli-responsive polymers, while complex viscous and elastic behavior hinders a deep understanding of functional polymers under external field excitation. Here, we demonstrate the in situ dynamic and static mechanical responses under electric stimuli of poly(methyl methacrylate) (PMMA) above glass transition temperature (Tg) by applying a direct current electric field vertically to the mechanical loading. The results show that the electro-mechanical response of PMMA is directly correlated to chain relaxation modes with different length scales: for local segments, polarization provides resistance for molecular motion, manifested by enhanced moduli, increased transient viscosity, and a wider linear viscoelastic range, whereas in a larger spatial range, polarization-induced conformation change causes faster relaxation, reduced elastic modulus, and a lowered modulus plateau. Moreover, flow viscosity is reduced because of weaker friction between chain segments under polarization. Our results suggest effective strategies for precisely tuning the viscoelastic behavior of polymers above Tg through electric stimuli. [ABSTRACT FROM AUTHOR] |
