Chemical Properties of 3a,6a-Diaza-1,4-diphosphapentalenes. Addition of p-Ditolyl Disulfide.

Autor: Sushev, V. V., Zolotareva, N. V., Grishin, M. D., Baranov, E. V., Fukin, G. K., Kornev, A. N.
Předmět:
Zdroj: Russian Journal of General Chemistry; 2023 Suppl 3, Vol. 93, pS713-S721, 9p
Abstrakt: Reaction of cyclohexane-annulated 3a,6a-diaza-1,4-diphosphapentalene with p-ditolyl disulfide gives the 1,4-adduct, while the double-decker ditriflate based on 2,3,5,6-tetramethyl-1H,4H-3a,6a-diaza-1,4-diphosphapentalene leads to the cross-deck adduct. The type of addition depends on the location of the HOMO: on the π-system of diazadiphosphapentalene in the first case, and in the interdeck space in the second. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
Externí odkaz: