| Autor: |
Audsley, Gabrielle, Carpentier, Ambre, Pécharman, Anne-Frédérique, Wright, James, Roseveare, Thomas M., Clark, Ewan R., Macgregor, Stuart A., Riddlestone, Ian M. |
| Předmět: |
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| Zdroj: |
Chemical Communications; 1/21/2024, Vol. 60 Issue 7, p874-877, 4p |
| Abstrakt: |
[Ni(IMes)2] reacts with chloroboranes via oxidative addition to form rare unsupported Ni-boryls. In contrast, the oxidative addition of hydridoboranes is not observed and products from competing reaction pathways are identified. Computational studies relate these differences to the mechanism of oxidative addition: B–Cl activation proceeds via nucleophilic displacement of Cl−, while B–H activation would entail high energy concerted bond cleavage. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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