| Autor: |
Brotsman, Victor A., Troyanov, Sergey I. |
| Předmět: |
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| Zdroj: |
Chemical Communications; 1/21/2024, Vol. 60 Issue 7, p893-896, 4p |
| Abstrakt: |
High-temperature chlorination of C76 fullerene with SbCl5 proceeds via five Stone–Wales rearrangements, resulting in non-classical (NC) C76(NC1a)Cl24 with two heptagons and 14 pentagons partically fused in pairs and triples. C76(NC2b)Cl28 with isomeric carbon cage was obtained by chlorination-promoted cage shrinkage of C80via two C2 losses. The pathways of skeletal cage trasformations, the chlorination patterns, and formation energies are discussed in detail. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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