Influence of donor point modifications on the assembly of chalcogen-bonded organic frameworks.

Autor: Eckstein, Brian J., Martin, Hannah R., Moghadasnia, Michael P., Halder, Arijit, Melville, Michael J., Buzinski, Tara N., Balaich, Gary J., McGuirk, C. Michael
Předmět:
Zdroj: Chemical Communications; 1/18/2024, Vol. 60 Issue 6, p758-761, 4p
Abstrakt: Incremental, single-atom substitutions of Se-based chalcogen bond (Ch-bond) donors with stronger donating Te centers were implemented in two new triptycene tris(1,2,5-chalcogenadiazole) tectons. The appreciably more favorable Ch-bonding ability of the Te-based donors promotes assembly of low-density networks and more stable Ch-bonded organic frameworks (ChOFs). [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index