N1-, N2-, and N3-Methyl-4-nitro-1,2,3-triazoles and Metal Complexes Based on Them.

Autor:	Filippova, Yu. V., Krupnova, I. A., Bosov, K. K., Sukhanov, G. T., Sukhanova, A. G., Pivovarova, E. V.
Předmět:	METAL complexes DIMETHYL sulfate COORDINATION compounds ALKYLATION COPPER compounds
Zdroj:	Russian Journal of Applied Chemistry; Mar2023, Vol. 96 Issue 3, p366-371, 6p
Abstrakt:	Alkylation of an NH-heterocycle, 4-nitro-1,2,3-triazole, with dimethyl sulfate is accompanied by tandem alkylation–quaternization and yields a complex mixture of products of N-monoalkylation at all the three heteroatoms, N-1, N-2, and N-3, with the significant prevalence of the N3 derivative and product of its further transformation, 1,3-dimethyl-4-nitro-1,2,3-triazolium salt. Previously unknown complexes of N3-methylnitrotriazole with copper(II) and nickel(II) ions were prepared. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink