| Autor: |
Zhang, Menglei, Li, Zhongkui, Zhu, Yanhong, Yan, Li, Zhong, Xue, Zhang, Yijie, Li, Ziyao, Bai, Yixiang, Li, Hui |
| Předmět: |
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| Zdroj: |
CrystEngComm; 1/21/2024, Vol. 26 Issue 3, p261-267, 7p |
| Abstrakt: |
The controllable synthesis of non-classical nucleobase pairs that can mimic partial biological behavior is very important for the in-depth study of DNA or RNA. Here, three different interaction modes of uracil–uracil base pairs (U-motif) have been explored in the coordination complexes of 2′-deoxyuracil 5′-monophosphate (dUMP) and uracil 5′-monophosphate (UMP) with transition metal ions by single crystal structural analysis and DFT calculations for the first time. The results indicate that the structural diversity of non-classical nucleobase pairs may be a bank of supramolecular interactions, which will contribute to the study of supramolecular chemistry and biochemistry. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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