| Autor: |
Assi, Navid, Lahoud, Christophe, Brázda, Petr, Zákutná, Dominika, Rainer, Daniel N., Hraníček, Jakub, Rohlíček, Jan, Tyrpekl, Václav |
| Předmět: |
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| Zdroj: |
New Journal of Chemistry; 1/21/2024, Vol. 48 Issue 3, p1071-1075, 5p |
| Abstrakt: |
Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f-elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to oxide. Structural determination of all intermediate nanocrystalline products was possible thanks to three-dimensional electron diffraction. This work reveals the enormous structural abilities of simple oxalate ligands. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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