| Autor: |
Tran, Hong Minh, Nguyen, Ngoc Tue, Nguyen, Xuan Truong, Nguyen, Duc-Trung, Giang, Thi Phuong Ly, Tran, Thuong Quang |
| Předmět: |
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| Zdroj: |
Chemical Engineering Communications; 2024, Vol. 211 Issue 3, p428-441, 14p |
| Abstrakt: |
In this work, we functionalized FeBDC by dosing Nitrogen-doped graphene quantum dots in order to improve the photocatalytic performance over Methylene Blue (MB) degradation. The novelty of this research is that N-doped graphene quantum dots (NGQ) were prepared by microwave irradiation Glycerol-Urea-Citric acid mixture, in which Glycerol could expand the sp2 domain of the NGQ. The effect of NGQ dosage on crystalline phases and porous properties of NGQ/FeBDC were thoroughly studied using X-ray Diffraction, Fourier-transform Infrared spectroscopy, and Nitrogen adsorption isotherm measurement. The optimal catalyst was 4-NGQ/FeBDC, with the doping percentage of NGQ in NGQ/FeBDC composite being at 4%wt. of the precursors. Some of the noticeable improvements of the 4-NGQ/FeBDC over the original FeBDC sample included a larger BET surface area (141.8 m2 g−1), wider optical absorption edge, a smaller bandgap energy (2.42 eV), and faster degradation reaction. The optimal sample was able to completely decompose MB within 50 minutes and could be repeatedly exploited 4 times. The morphology of 4-NGQ/FeBDC particles was polyhedron shape with NGQ covering around, confirmed by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) images. Some parameters that affect MB degradation of the 4-NGQ/FeBDC would be investigated, covering light irradiation, H2O2 presence, initial pH of MB solution, and reusability. The regeneration procedure of the optimal photocatalysts as well as the electron transfer mechanism within the photocatalytic system would be proposed in this paper. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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