| Autor: |
Ulitin, N. V., Novikov, N. A., Tereshchenko, K. A., Shiyan, D. A., Lyulinskaya, Ya. L., Nurullina, N. M., Denisova, M. N., Stoyanov, O. V., Kharlampidi, Kh. E. |
| Zdroj: |
Polymer Science -- Series D; Dec2023, Vol. 16 Issue 4, p928-935, 8p |
| Abstrakt: |
A kinetic modeling was carried out for the synthesis of cumene hydroperoxide (an initiator of curing for acrylic adhesives) based on cumene oxidation in the presence of Mg, Ca, Sr, or Ba 2-ethylhexanoate as a catalyst. The kinetic model includes the formation reactions of intermediate components of the reaction mixture–catalyst adducts, the initiation reactions, the propagation and chain termination reactions, and molecular reactions characterizing both noncatalytic and catalytic cumene oxidation, as well as specific reactions caused by the catalytic properties of 2-ethylhexanoates of nontransition metals. The kinetic model reproduces the concentrations of reaction mixture components depending on time within the experimental data error, which confirms the kinetic scheme included in the model. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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