| Autor: |
Mishra, Gitanjali, Sasmal, Mukesh, Chakraborty, Arundhuti, Thirupathi, Barla |
| Předmět: |
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| Zdroj: |
Chemistry - A European Journal; 12/19/2023, Vol. 29 Issue 71, p1-7, 7p |
| Abstrakt: |
Synthesis of highly functionalized spiro[4.4]nonane and spiro[4.5]decane motifs by the reaction of dimethylacetylenedicarboxylate (DMAD) with 2‐(2′‐ketoalkyl)‐1,3‐indandiones and 2‐(3′‐ketoalkyl)‐1,3‐indandiones, respectively, has been developed by utilizing a catalytic amount of DABCO. The tertiary hydroxy‐containing spiro[4.4]nonane products were converted into fully conjugated pentafulvene π‐systems in an acidic medium through dehydration and unprecedented C−C bond rearrangement. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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