Desalination of aqueous solutions using interpenetrating polymeric membranes-integrated zeolite through pervaporation and reverse osmosis.

Autor: Jafarian, Masoud, Malekpour, Akbar, Koohmareh, Gholam Ali
Zdroj: Desalination & Water Treatment; 2/28/2023, Vol. 286, p16-28, 13p, 2 Black and White Photographs, 4 Charts, 12 Graphs
Abstrakt: An interpenetrating polymer network (IPN) membrane and its modified form with NaA zeolite were prepared using polyvinyl alcohol/polyacrylic acid and were used in desalination of saline solutions by pervaporation and reverse osmosis. The prepared membranes were characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, tensile and swelling test. The effective parameters in the membrane preparation were investigated and optimized through experimental design. Then, Salt rejection and solution flux were selected as the criteria for the membrane performances. The pervaporation results showed that the flux increases with the feed temperature going up and the membrane thickness decrease. However, better rejection was achieved at less feed temperature and more membrane thickness. At the optimized conditions, flux 7.1 kg/h·m2 and rejection 99% were obtained by net IPN membrane while, these parameters were changed to 11.2 kg/h·m2 and up to 95% by IPN/NaA membrane. Reverse osmosis experiments revealed that as the pressure on the membrane increases, the amount of flux goes up, while it requires less pressure and more cross-linked membrane for having higher rejection (flux 16.2 kg/h·m2 and rejection 90%). According to the obtained results, it was found that this composite membrane has a high ability in desalination with appropriate rejection and fluxes. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index