The Possibility of Saturation Transfer in a New Nickel(II) Complex with 2,6-Bis(pyrazol-3-yl)pyridine.

Autor:	Aleshin, D. Yu., Nikovskii, I. A., Khakina, E. A., Dan'shina, A. A., Nelyubina, Yu. V.
Předmět:	MAGNETIZATION transfer PYRIDINE NUCLEAR magnetic resonance spectroscopy NICKEL ELEMENTAL analysis MASS spectrometry
Zdroj:	Russian Journal of Coordination Chemistry; Dec2023, Vol. 49 Issue 12, p777-783, 7p
Abstrakt:	The reaction of N,N '-disubstituted 2,6-bis(pyrazol-3-yl)pyridine ligand (L) with a divalent nickel salt gave a new nickel(II) complex [Ni(L)(H2O)(THF)Cl]BPh4 (I), which was isolated in a pure state and characterized by elemental analysis, mass spectrometry, NMR spectroscopy, and X-ray diffraction (CCDC no. 2221412). According to NMR spectroscopy data combined with the results of quantum chemical calculations, complex I does not show saturation transfer effect in solutions. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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