| Autor: |
Petrov, P. A., Nikolaevskii, S. A., Yambulatov, D. S., Starikova, A. A., Sukhikh, T. S., Kiskin, M. A., Sokolov, M. N., Eremenko, I. L. |
| Zdroj: |
Russian Journal of Inorganic Chemistry; Sep2023, Vol. 68 Issue 9, p1228-1236, 9p |
| Abstrakt: |
The heteroleptic anionic complex (IPrPhH)[Co2(μ-Piv)2(μ-OSiMe3)(Piv)2] (I) was synthesized through the reaction of cobalt pivalate [Co(Piv)2]n with 1,3-bis(2,6-diisopropylphenyl)-2-phenylimidazolium iodide ([IPrPhH]I) and KN(SiMe3)2 and studied by X-ray diffraction both in the solvate-free form and in the form of solvate with pentane (I⋅0.75C5H12) (CCDC 2257678–2257679). Modeling of the probable mechanism of formation of complex I and evaluation of exchange coupling between paramagnetic centers in it were carried out by density functional theory method. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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