Zinc Complexes Containing Substituted 1,10-Phenanthrolines as Ligands: Synthesis, Structure and Application as Initiators of ε-Caprolactone, Rac- and L-Lactides Polymerization.

Autor:	Agaeva, M. U., Mankaev, B. N., Filippenko, V. I., Lysenko, K. A., Egorov, M. P., Karlov, S. S.
Předmět:	ZINC compounds RING-opening polymerization POLYMERIZATION LIGANDS (Chemistry) NUCLEAR magnetic resonance spectroscopy ELEMENTAL analysis X-ray diffraction
Zdroj:	Russian Journal of General Chemistry; Nov2023 Suppl 1, Vol. 93, pS304-S316, 13p
Abstrakt:	Zinc complexes X2Zn(L) (X = Et, OAc, OC(O)CF3)) were synthesized in which 1,10-phenanthrolines containing substituents at positions 2, 4, 7, and 9 were used as bidentate ligand L. The structures of the complexes were confirmed by NMR spectroscopy and elemental analysis. The structures of three complexes were investigated by X-ray diffraction analysis. The complexes have been studied as initiators of ε-caprolactone, L- and rac-lactides polymerization. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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