Effects of Azomethine Derivatives of 4,6-Di-tert-Butyl-2,3-Dihydroxybezaldehyde on Radiation-Induced Reactions Involving Alkyl and Alpha-Hydroxyalkyl Radicals.

Autor:	Ksendzova, G. A., Ostrovskaya, N. I., Sverdlov, R. L., Sorokin, V. L.
Předmět:	SCHIFF bases RADICALS (Chemistry) RADIOLYSIS ALKYL radicals CATECHOL HEXANE
Zdroj:	High Energy Chemistry; Dec2023, Vol. 57 Issue 6, p489-493, 5p
Abstrakt:	The effects of azomethine derivatives of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde on the formation of radiolysis products of deaerated n-hexane and ethanol have been studied. It was shown that the catechol moiety in the tested compounds did not significantly affect their reactions with carbon-centered radicals. The aldimine group exhibited high activity as an α-hydroxyalkyl radical scavenger and low activity as a scavenger of alkyl radicals. The introduction of additional radical-inhibiting groups –OH, –SH, –NO2, and =N–NH– into the side fragment of a molecule led to a significant increase in the antiradical activity with respect to various types of carbon-centered radicals. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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