Double-stranded metallo-triangles: from anion-templated nonanuclear to cation-templated tetraicosanuclear dysprosium clusters.

Autor: Liu, Yanan, Sun, Xiao, Chen, Peiqiong, Li, Xiaojuan, Huang, Fu-Ping, Liu, Hou-Ting, Tian, Haiquan
Předmět:
Zdroj: Chemical Communications; 12/11/2023, Vol. 59 Issue 95, p14134-14137, 4p
Abstrakt: Two double-stranded metallo-triangles, Dy9 and Dy24, with hexaple-C10H7PO32− bridges were constructed, and their magnetic properties were explored. Compared with the field-induced relaxation phenomenon of Dy9 templated with a chloride anion, Dy24 templated with a sodium cation exhibited zero-field single-molecule-magnet behavior. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index