| Autor: |
Zhao, Jie, Li, Zi‐Yu, Yang, Chun‐Xu, Li, Ya‐Ping, Liu, Yu‐Shen, Hu, Zhen Hua, Pan, Xiao‐Ming, Ma, Xiu‐Li, Wang, Wei, Yang, Xiao‐Shuai, Wang, Lu‐Liang |
| Předmět: |
|
| Zdroj: |
Journal of the Science of Food & Agriculture; Jan2024, Vol. 104 Issue 1, p257-265, 9p |
| Abstrakt: |
BACKGROUND: Phenolic endocrine‐disrupting chemicals (EDCs) are widespread and easily ingested through the food chain. They pose a serious threat to human health. Magnetic solid‐phase extraction (MSPE) is an effective sample pre‐treatment technology to determine traces of phenolic EDCs. RESULTS: Magnetic covalent organic framework (COF) (Fe3O4@COF) nanospheres were prepared and characterized. The efficient and selective extraction of phenolic EDCs relies on a large specific surface and the inherent porosity of COFs and hydrogen bonding, π–π, and hydrophobic interactions between COF shells and phenolic EDCs. Under optimal conditions, the proposed magnetic solid‐phase extraction‐high‐performance liquid chromatography–ultra violet (MSPE‐HPLC‐UV) based on the metallic covalent organic framework method for phenolic EDCs shows good linearities (0.002–6 μg mL−1), with R2 of 0.995 or higher, and low limits of detection (6–1.200 ng mL−1). CONCLUSION: Magnetic covalent organic frameworks (Fe3O4@COFs) with good MSPE performance for phenolic EDCs were synthesized by the solvothermal method. The magnetic covalent organic framework‐based MSPE‐HPLC‐UV method was applied successfully to determine phenolic EDCs in beverage and water samples with satisfactory recoveries (90.200%–123%) and relative standard deviations (2.100%–12.100%). © 2023 Society of Chemical Industry. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
Plný text