Stabilization of Guanidinate Anions [CN3]5− in Calcite‐Type SbCN3.

Autor: Brüning, Lukas, Jena, Nityasagar, Bykova, Elena, Jurzick, Pascal L., Flosbach, Niko T., Mezouar, Mohamed, Hanfland, Michael, Giordano, Nico, Fedotenko, Timofey, Winkler, Björn, Abrikosov, Igor A., Bykov, Maxim
Předmět:
Zdroj: Angewandte Chemie; 11/20/2023, Vol. 135 Issue 47, p1-6, 6p
Abstrakt: The stabilization of nitrogen‐rich phases presents a significant chemical challenge due to the inherent stability of the dinitrogen molecule. This stabilization can be achieved by utilizing strong covalent bonds in complex anions with carbon, such as cyanide CN− and NCN2− carbodiimide, while more nitrogen‐rich carbonitrides are hitherto unknown. Following a rational chemical design approach, we synthesized antimony guanidinate SbCN3 at pressures of 32–38 GPa using various synthetic routes in laser‐heated diamond anvil cells. SbCN3, which is isostructural to calcite CaCO3, can be recovered under ambient conditions. Its structure contains the previously elusive guanidinate anion [CN3]5−, marking a fundamental milestone in carbonitride chemistry. The crystal structure of SbCN3 was solved and refined from synchrotron single‐crystal X‐ray diffraction data and was fully corroborated by theoretical calculations, which also predict that SbCN3 has a direct band gap with the value of 2.20 eV. This study opens a straightforward route to the entire new family of inorganic nitridocarbonates. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
Externí odkaz:
Nepřihlášeným uživatelům se plný text nezobrazuje